Particulate matter from aircraft engines affects airways

According to the World Health Organization (WHO), seven million people worldwide die as a consequence of air pollution every year. For around 20 years, studies have shown that air-borne particulate matter negatively affects human health. Now, in addition to already investigated particle sources like emissions from heating systems, industry and road traffic, aircraft turbine engine particle emissions have also become more important.

Photo of Alouette III No 196 showing soiling of the tail boom with soot from exhaust gasses.

In a unique, innovative experiment, researchers have investigated the effect of exhaust particles from aircraft turbine engines on human lung cells.

The cells reacted most strongly to particles emitted during ground idling.

It was also shown that the cytotoxic effect is only to some extent comparable to that of particles from gasoline and diesel engines.The primary solid particles, i.e. those emitted directly from the source, have the strongest effect on people in its immediate vicinity. 

Now a multidisciplinary team, led by lung researcher Marianne Geiser of the Institute of Anatomy at the University of Bern, together with colleagues from Empa Dübendorf and the University of Applied Sciences and Arts Northwestern Switzerland (FHNW), has shown that primary soot particles from kerosene combustion in aircraft turbine engines also cause direct damage to lung cells and can trigger an inflammatory reaction if the solid particles are inhaled in the direct vicinity of the engine.

The researchers demonstrated for the first time that the damaging effects also depend on the operating conditions of the turbine engine, the composition of the fuel, and the structure of the generated particles.

Beechcraft 200 Super King Air No 240 showing soiling of the engine panels with soot from exhaust gasses.

Extremely small particles in the nanoscale range

Particles emitted from aircraft turbine engines are generally ultrafine, i.e. smaller than 100 nm. By way of comparison, a human hair has a diameter of about 80,000 nm. When inhaled, these nanoparticles — like those from other combustion sources -efficiently deposit in the airways. In healthy people, the well-developed defense mechanisms in the lungs normally take care of rendering the deposited particles ineffective and removing them from the lungs as quickly as possible.

However, if the inhaled particles manage to overcome these defense mechanisms, due to their structure or physico-chemical properties, there is a danger for irreparable damage to the lung tissue. This process, already known to researchers from earlier experiments with particle emissions from gasoline and diesel engines, has now also been observed for particle emissions from aircraft engines.

Toxicity depends on the operating conditions of the turbines and the type of fuel

Evidence of increased cell membrane damage and oxidative stress in the cell cultures was identified. Oxidative stress accelerates ageing of cells and can be a trigger for cancer or immune system diseases.

Overall, according to the researchers, it has been demonstrated that the cell-damaging effect caused by exposure to particles generated by the combustion of gasoline, diesel and kerosene fuel are comparable for similar doses and exposure times.

Additionally, a similar pattern was found in the secretion of inflammatory cytokines after exposure to gasoline and kerosene fuel particles.

Aerosols: distance from the source is crucial

Aerosols are the finest solid or fluid substance suspended in the air. In combustion processes, the composition of ultrafine particles is highly variable. In addition, aerosols are unstable, and they are modified after their formation. Primary ultrafine solid particles have a high diffusion velocity. As a result, at high concentrations such particles either stick together or attach to other particles. Therefore, the effect of primary ultrafine particles depends on the distance from the source, implying that there is a difference depending on whether a person is close to the source (such as people at the roadside ) or at a greater distance (aircraft taxiing or taking off). Further research is needed to clarify how strong the impact would be at a greater distance from an aircraft engine

Read full article in ScienceDaily

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The layout of the Irish Air Corps base at Casement Aerodrome ensures that aircraft exhaust gasses are blown over populated sections of the airbase when winds are from the south, south east or south west. This includes hangars, offices, workshops and living in accommodation such as the apprentice hostel and married quarters. Calm weather also creates conditions where exhaust gasses linger in higher concentrations.

This results in all Irish Air Corps personnel (commissioned, enlisted, civilian & family) being exposed to emissions from idling aircraft engines, emissions that are known to cause harm.

In the mid 1990s a study of air pollution adjacent to the ramp area at Baldonnel was commissioned. This report relating to this study has gone missing. 

  • Anecdotal evidence suggests increased prevalence of occupational asthma & adult onset asthma amongst serving & former personnel who served in Baldonnel or Gormanston aerodromes. 
  • Older gas turbine engines produce dirtier exhaust gasses.
  • Idling gas turbine engines produce dirtier exhaust gasses.
Below are some of the gas turbine powered Air Corps aircraft that were powered by elderly engine designs.
AircraftRetiredEngine FamilyFirst Run
Alouette III2007Turbomeca Artouste1947
Fouga Magister1999Turbomeca Marboré1951
Gazelle2005Turbomeca Astazou1957
King Air 2002009Pratt & Whitney Canada PT61960
Dauphin II2005Turbomeca Arriel1974

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RAAF jet fuel damaged ground crews’ body cells; long-term consequences unknown, says groundbreaking research

Royal Australian Air Force (RAAF) personnel who worked with widely used jet fuel suffered damage to their body’s cells with unknown long-term consequences, according to groundbreaking research released after a Freedom of Information laws request.

Defence’s senior physician in occupational and environmental medicine, Dr Ian Gardner, described the findings as a “part of the puzzle” and a hypothesis-making study”, and pointed it out that it was one of a series of pieces of research currently underway.

“What it shows is there is evidence of small but persistent cellular damage,” Dr Gardner told the ABC. He said it was not yet clear what the long-term effects of that damage might be.

“For the future though there are a lot of other aircraft maintenance workers who have done similar jobs on other aircraft types, and now Defence and DVA and Air Force are considering what additional work should be done in relation to those other people who are not actually on the F-111 programs but have done essentially similar work,” Dr Gardner said.

The Jet Fuel Syndrome Study also shows that the fuel is more toxic to the body’s cells than the two solvents initially blamed for the sickness suffered by the deseal/reseal workers, and that the toxicity is even higher when those solvents and the fuel were mixed.

The results of the research project, headed by Professor Francis Bowling of Brisbane’s Mater Hospital, were handed to Defence last September, and have been the subject of significant scrutiny and review due to the potential significance of the findings.

They will give heart to former and serving Defence personnel who believe they have been left out in the cold by Defence after developing serious health complaints while working with fuel and other substances.

Read full article on ABC Australia from 2015

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Junior Minister with responsibility for Defence said in the Dáil that he was assured by the Irish Air Corps that the RAAF F1-11 deseal/reseal exposure tragedy is completely different to any exposures at the Irish Air Corps.

Was the minister suggesting that Irish Air Corps gas turbine engines don’t run on jet fuel?

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Army blames Covid-19 for continued failure to give affidavit to former Air Corps mechanic

Dutch Neurologist Warns of ‘Parkinson’s Pandemic’ Linked to Toxic Chemicals

As the world frantically battles coronavirus, a leading Dutch neurologist warns of the next global pandemic — and this one, he says, is almost entirely of our own making.

Bastiaan Bloem, MD, a neurologist and professor at Radboud University Nijmegen Medical Center, says that over the next 20 years, the number of people with Parkinson’s disease (PD) will likely double — from the present 6.5 million to more than 13 million.

The main cause of this exponential jump: widespread exposure to herbicides, solvents, and other toxic chemicals used in agriculture and manufacturing.

“A pandemic, as everybody is now painfully aware, is a disease happening worldwide, to which no one is immune. PD fulfills all those criteria,” Bloem told Parkinson’s News Today in a phone interview from the Netherlands.

“Parkinson’s is now the fastest-growing neurological condition on the planet.”

Bloem, 53, points to the tight link between exposure to herbicides such as paraquat — a weed killer — and the risk of developing Parkinson’s.

“These chemicals were introduced worldwide after World War II, and many are still used today on our fields,” he said. “For this reason, farmers are at a markedly increased risk of developing Parkinson’s. If you feed a mouse paraquat — which is banned in China but not the U.S. — it will kill the dopamine-producing cells in the brain. These chemicals are tremendously toxic to the brain and have even been detected in milk, in supermarkets.”

Paraquat isn’t the only such chemical posing this risk. Trichloroethylene, a solvent used to clean metals and remove stains, has exactly the same effect on human brains. Yet it’s still widely used and is detectable in high concentrations in groundwater, he said.

“Parkinson’s is exploding in numbers, it’s a horribly debilitating disease, and it’s a costly disease that should matter to people and governments. We’re doing this to ourselves,” Bloem said. “But we can do something about it. We need to get rid of these toxic pesticides and move toward organic food. And we should take measures to protect people who work in these toxic environments.”

Read full article Parkinson’s News Today

Dutch Neurologist Warns of ‘Parkinson’s Pandemic’ Linked to Toxic Chemicals

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Trichloroethylene was used in Baldonnel for decades with ERF in particular receiving it in 220 litre drums. From ERF it was handed out without any precautions or training to anyone who asked for it. It was handed out in milk cartons, plastic coke bottles etc.

Trichloroethylene was used by all hangars & workshops in an ad-hoc basis usually with Trichloroethylene begged from ERF although some units did order it themselves. Personnel in the Air Corps museum also used Trike to help degrease parts & aircraft being restored for the museum. 

Trichloroethylene was also used by both apprentices, tech & line personnel to carry out cleaning tasks in the Air Corps Training Depot while on training courses or during “war week”.

In at least 2 separate instances some floors in ACTD were completely destroyed by the use of Trichloroethylene being left overnight to clean them. In one incident Trichloroethylene dissolved through a traditional lino floor as far as the backing twine and in another incident few years later a tiled floor was destroyed after the tiles shriveled up & shrunk after Trichloroethylene  was left overnight to clean a floor.

Trichloroethylene was also used by teenage apprentices to clean black marks off floors in the Apprentice Hostel and the Apprentice School.

At no point was anyone ever given training in the use of Trichloroethylene nor issued with appropriate PPE whilst working with the chemical.

A number of Irish Air Corps personnel have been diagnosed with early onset Parkinson’s disease

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Investigation after bag suspected to contain cocaine found at Baldonnel airbase

An investigation has been launched after a bag suspected to contain cocaine was found at the Baldonnel airbase.

Officers Mess – Baldonnel

According to a Defence Forces source, the bag was found outside the Officers’ Mess car park last night.

A spokesperson for the Air Corps said: “I can confirm that an unknown substance was recovered in an area of unused ground in Casement Aerodrome, Baldonnel.

“A Military Police investigation has commenced.

“Óglaigh na hÉireann does not comment on ongoing Military Police Investigations.”

Solvent exposure and Parkinson’s disease

Shaun Wood worked was a painter and finisher  at Royal Air Force (RAF) bases across the world. During the early 1990s he was involved in the very intensive work preparing Tornado aircraft for the first Gulf War, in particular gluing anti-missile patches to the aircraft. This work was often done in confined spaces over long working hours.  He generally wore a respirator but these were not really adequate for the circumstances.

German Tornado Undergoing Maintenance

Shaun has been diagnosed with Multiple System Atrophy (MSA), which is a debilitating Parkinsonian syndrome that affects the nervous system. He is just 53 years of age.

Throughout his work Shaun was exposed to various solvents, but primarily trichloroethylene and dichloromethane. There is not a great deal of information about exposure to these solvents in aircraft maintenance. I have seen results from a survey carried out at an RAF base in Scotland where dichloromethane levels were measured during paint striping in the cockpit area of a Nimrod aircraft. There was only 1.5 m2 of paint removed, but the peak air concentrations were about 700 mg/m3. Results from three monitoring surveys where the British Health and Safety Executive sampled for dichloromethane during paint stripping on aircraft are shown in the following figure. The mean levels measured in each of these surveys were: 330, 790 and 1,960 mg/m3, and the highest individual level measured was 3,590 mg/m3.

Read full article on OH-world.org A blog about exposure science and occupational hygiene

http://johncherrie.blogspot.ie/2011/12/solvent-exposure-and-parkinsons-disease.html

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Below is a photo of one of the locations in the Irish Air Corps that used Dichloromethane, namely the NDT Shop of Engine Repair Flight. Yes that is a stream of the chemicals dripping out of the extractor fan and running down the wall. And yes that is dichloromethane, cresylic acid and the hexavalent sodium chromate all over the floor. The small barrel that is being dissolved by its contents contains Hydrofluoric Acid.

Some extracts from the Ambient Air Monitoring For Health and Safety at Work report dated 2nd August 1995

  1. Dichloromethane levels were measured in the engine shop in Wednesday the 12th and Thursday the 13th of July 1995 at the behest of Captain John Maloney who is still serving in the Irish Air Corps
  2. The level of dichloromethane found in ambient air in the engine
    cleaning area exceeded health and safety limits. 
  3. Levels of Dichloromethane were measured at 175.9ppm (622.5 mg/m3)  while the TWA health & safety limit for this chemical in 1995 was 50ppm.
  4. Significant levels of all parameters monitored were found in nearly all ambient air samples taken in the engine cleaning area.
  5. The ventilation in all areas monitored was deemed to be insufficient. It is thus recommended that mechanical heating and ventilation systems be adapted designed and installed in all areas monitored.

To summarise, the Irish Army Air Corps knew that Dichloromethane levels in the NDT shop in 1995 exceeded health & safety limits by 3.5 times yet officer management

  1. LEFT personnel of all ranks and none to rot in this exceptionally toxic working environment for a further 12 years.
  2. IGNORED the recommendation to design and install design a proper ventilation system, (they stuck in 2 x Xpelairs).
  3. NEVER re-tested the environment to see if the Xpelair fans worked, we suspect they made things worse by increasing evaporation rate.
  4. NEVER informed personnel of enlisted ranks that their workplace was contaminated to dangerous levels.

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Leo Varadkar urged to act on Air Corps chemical exposure ‘legacy’

Taoiseach Leo Varadkar has said he believes the courts should decide whether former Air Corps staff are suffering chronic illnesses due to chemical exposure.

Mr Varadkar made the comments yesterday in the Dáil where Sinn Féin Defence Spokesperson Aengus O’Snodaigh repeated calls for a health study of Air Corps members, similar to an analysis of Australian Air Force staff, which found technicians who worked with carcinogenic chemicals were at greater risk of illness.

Last year, the Irish Examiner revealed the State is facing a number of claims from former staff, and that whistleblowers had raised concerns about the safety of workers using chemicals at Casement Aerodrome, Baldonnel.

“While I have absolutely no doubt that the serious ill-health suffered by some former members of the Air Corps is real, it has not been proven whether this array of illnesses could be caused by chemical exposure,” Mr Varadkar said.

“There is litigation in the courts, which are the best place to assess the evidence and see whether the allegations are supported by that evidence,” he said.

Mr O’Snodaigh said a survey is needed as the implications of widespread staff exposure to the chemicals used goes beyond the seven cases currently against the State. “We do not want to be here in 10 years’ time with a higher death toll, having failed to address this scandal,”he said.

Read full article on Irish Examiner website below…

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The vast majority of Irish Air Corps Chemical Abuse Survivors are not currently engaged in legal action. For these serving and former personnel the Taoiseach is offering them no respite, not assistance and no hope.

Hexamethylene Diisocyanate – Just one of the toxic chemicals the Irish Air Corps and State Claims Agency want to hide from former personnel!

  1. Exposure can occur when isocyanates are curing or when cured isocyanates are heated.
  2. An individual’s response to isocyanate exposure can be immediate or may be DELAYED FOR SEVERAL YEARS.
  3. Skin exposure can also cause respiratory sensitisation.
  4. The odour threshold for isocyanates, i.e. the level at which an individual can smell an isocyanate, is typically higher than the allowed exposure limits.
  5. The Air Corps did eventually provide a “supplied air” respirator to spray paint & welding personnel. Unfortunately they sourced the “supplied air” from an old machine compressor located in ERF where the air had previously tested as 3.5 times over the allowed limit for Dichloromethane i.e. allowed limit was 50ppm and sourced air was from a location measured at 175ppm…out of the frying pan and into the fire.

Air Corps Hexamethylene Diisocyanate Usage

Hexamethylene Diisocyanates were a chemical component of polyurethane paint hardener used by the Spray Paint Shop (Dope Shop) at Baldonnel. For most of the existence of this shop personnel were NOT supplied with ANY PPE. The walls between the Spray Paint Shop and Engineering Wing Hangar & Workshops were not sealed and so Hexamethylene Diisocyanate and other chemicals entered these workplaces whilst spraying was in progress exposing all personnel.

Furthermore if a component could not be removed from an aircraft for spray painting it was spray painted in-situ in Engineering Wing Hangar whilst unprotected line & tech personnel worked in adjoining offices & workshops or on other aircraft in the hangar.

Visiting personnel to Engineering Wing hangar such as BFTS personnel doing an IRAN, Heli personnel doing an overhaul & even Military Police on a walkabout were also exposed.

A “waterfall” system with an extractor fan was also present. Personnel spray painted aircraft components toward the waterfall which captured most of the over-spray droplets. Fumes from this waterfall were then extracted by a fan, up a duct and released at approximately 3m height where the prevailing winds then carried the extracted fumes in the doors & windows of : 

  • 5th Maintenance Engineers
  • Air Corps Apprentice School
  • Avionics Squadron
  • BFW Stores
  • Engine Repair Flight
  • Old Tech Stores
  • Training Wing HQ Prefab
  • Parachute Shop

5-20% of people are prone to isocyanate sensitisation. and isocyanate cross sensitisation is a recognised phenomenon. Sensitisation is irreversible and unfortunately once sensitised it is next to impossible to avoid isocyanate allergy triggers in the modern environment as they are used to make all Polyurethane products.

It is also likely that health effects are suffered beyond the respiratory system & skin for example the gastric & nervous systems and it is also probable that sensitisation to isocyanates will lead to allergies to other unrelated chemicals leading to a cascade of triggering chemicals allergies & intolerance for over exposed individuals.

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Navy (New Zealand) veteran’s landmark compensation deal has others with Parkinson’s fearing trichloroethylene

Hundreds of New Zealanders may have been affected by a toxic chemical in a wide range of workplaces, a Weekend Herald investigation has found.

The discovery follows a landmark compensation pay-out to a New Zealand navy veteran who proved links between exposure to the solvent during his military service and his Parkinson’s disease.

The Herald reported last month that Veterans Affairs has provided the ex-serviceman with an entitlement to disability compensation for Parkinson’s, a condition attributed to his exposure to trichloroethylene (TCE) while degreasing and cleaning electronics on a Royal New Zealand Navy ship during the 1948-1960 Malayan Emergency.

The Weekend Herald has since tracked down other men who fear their handling of TCE in the 1960s, 70s, and 80s could have caused their debilitating diseases and who now want to pursue their own compensation cases.

A former New Zealand Post Office telephone exchange technician, a naval dockyards apprentice and an aircraft engineer have all spoken about using TCE in their workplaces for years, without any health and safety precautions.

None of them used gloves or breathing apparatus while being exposed to the potent halocarbon that was popular across an array of sectors and workplaces in New Zealand, including garages, railway and aircraft workshops, and other depots.

“Trichlo was strong enough to bowl you over,” said 65-year-old Steve Walker, an ex-New Zealand Post Office employee at the Balclutha exchange, who now struggles with Parkinson’s. “It seeped into your skin, into your clothes. It took over you completely.”

Dave Schafer, a 58-year-old who used TCE weekly while cleaning instruments on Navy frigates during a five-year apprenticeship at the Devonport naval base, said: “Holy cow, that stuff was powerful. But as apprentices you kept your mouth shut and did your job, you didn’t rock the boat.”

Parkinson’s New Zealand, the Returned and Services’ Association (RSA), and those spoken to by the Weekend Herald, all believe there will be many more New Zealanders – hundreds if not thousands – who have been exposed to TCE over the years.

“Researchers have suggested there could be a significant lag time between exposure to TCE and the onset of Parkinson’s,” said Parkinson’s New Zealand chief executive Deirdre O’Sullivan.

“As such, we have reason to believe there could be many more serving and/or ex-serving NZDF people in a similar situation to this veteran.”

The potentially precedent-setting Navy veteran’s decision was made on appeal to the independent Veterans’ Entitlements Appeal Board, which considered appeals against decisions made under the War Pensions Act 1954.

It was made possible by ground-breaking international research including a major 2011 study on TCE exposure that concluded it was likely to result in a sixfold increase in the chances of developing Parkinson’s.

Read more on the New Zealand Herald’s website

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Interesting that the New Zealand Herald article discusses exposure in the 1960s, 70s, and 80s. No mention of the 1990s onwards obviously because the industries there using the chemical copped on in the 1990’s.

Unfortunately the Irish Air Corps was still exposing personnel to Trike, (without protection) in ERF / Avionics in the 1990s and well into the first decade of this century and likely elsewhere in Baldonnel & Gormanston

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Safe Handling of Cresols, Xylenols & Cresylic Acids

Introduction

Cresols, xylenols and cresylic acids are hazardous substances and dangerous both to people and the environment if handled improperly. Cresols, xylenols and cresylic acid products produced by Sasol Chemicals (USA) LLC are highly versatile materials and are used as intermediates in the manufacture of a wide variety of industrial products such as resins, flame retardants, antioxidants, and coatings. In these and other applications, cresylic acids can be stored, transferred, processed and disposed of safely when proper procedures and safeguards are used. 

“Cresol” refers to any of the three isomers of methylphenol (C7H8O) or combinations thereof. “Cresols” commonly refer to a mixture which is predominantly methylphenol but may also contain lesser amounts of other alkylphenols. “Xylenol” is a common name for any of the six isomers of dimethylphenol (C8H10O) or their various combinations. Material which is predominantly dimethylphenol but which also contains ethylphenols and other alkylphenols may be referred to as “Xylenols”. “Cresylic acid” is a generic term referring to various combinations of cresols, xylenols, phenol or other alkylphenols (ethylphenols, propylphenols, trimethylphenols, etc.). 

Purpose & Scope

The purpose of this document is to provide information gathered through Sasol’s long experience in the safe handling of cresylic acids. It focuses on basic and practical information about working safely with these substances. Additional references are provided and it is strongly recommended that these and others be consulted prior to working with cresylic acids. Please do not hesitate to contact your regional Sasol office if we can be of assistance in the safe storage, handling, processing and disposal of our products.

Hazards

Health Hazards

The primary dangers posed in handling cresylic acids are those resulting from physical exposure. Cresylic acids are highly corrosive and contact with exposed skin or mucous membranes causes severe burns. These burns progress from an initial whitening of the exposed skin to blackishbrown necroses within 24 hours after exposure. Cresylic acids also exhibit anesthetic properties. Therefore, victims frequently misjudge the extent of their exposure when the initial burning sensation rapidly subsides. This can result in prolonged contact, causing toxic effects in addition to the corrosive damage. 

Cresylic acids are readily absorbed through the skin and mucous membranes in liquid or vapor form and act as systemic toxins for which there is no established treatment. Relatively small areas of exposure (e.g. an arm or a hand) can allow sufficient absorption to cause severe poisoning. Progressive symptoms of such poisoning include headache, dizziness, ringing in the ears, nausea, vomiting, muscular twitching, mental confusion, loss of consciousness and, possibly, death from lethal paralysis of the central nervous system. Chronic exposure can lead to loss of appetite, vomiting, nervous disorders, headaches, dizziness, fainting and dermatitis. 

The Occupational Health & Safety Administration (OSHA) has established 5ppm or 22 mg/m3 permissible exposure limits (PEL’s) for cresols on an 8-hour time-weighted average basis. OSHA guidelines also indicate that adequate personal protective equipment (PPE) should be employed to avoid skin contact with cresols. Cresylic acids are not listed as carcinogens by OSHA, the International Agency for Research on Cancer (IARC) or the National Toxicology Program (NTP).

Environmental Hazards

Cresylic acids show high acute toxicity towards both fish and aquatic invertebrates and must be prevented from entering surface or ground waters. Depending upon the specific composition, the material may be classified as a marine pollutant. Please refer to the current label and safety datasheet.

Controls for Working with Cresols

Safe storage, handling, processing and disposal of cresylic acids begin long before they ever arrive on-site. Measures necessary to ensure the health and well-being of employees, customers, the community and the  environment include the development of effective administrative and engineering controls designed to specifically address the hazards associated with cresylic acids. Personal protective equipment (PPE) is integral to safe handling and should be viewed as the last line of defense against an accidental failure of the administrative and/or engineering controls. 

Administrative Controls

Administrative controls are the foundation of any program designed for safely handling cresylic acids. Every company is unique in how they run their business and establish administrative controls. Those specifically developed for working with cresylic acids should address comprehensive process planning, thorough communication of hazards to employees and extensive training of employees on the proper implementation of all safety measures.

Personal Protective Equipment (PPE)

All personnel who work with or near cresylic acids must use adequate personal protective equipment (PPE). The extent of the potential exposure and consideration of established permissible exposure limits (PEL’s) should dictate the level of protection necessary. Personnel working with or near lab-scale quantities should always wear safety glasses with side-shields or

chemical mono-goggles, chemical-resistant or impermeable gloves, long-sleeved shirts and trousers as a minimum.

Circumstances such as elevated temperature and pressure or vacuum conditions should dictate if more substantial protection is necessary, including face shields, chemically impermeable outerwear, and breathing protection. Personnel transferring larger quantities of cresylic acids, or working in areas where a line-break could result in similar exposure, should always wear full protective equipment.

Emergency Procedures

Physical Exposure – External

The primary dangers involved in working with cresylic acids are the corrosive and toxic effects resulting from a physical exposure. Studies suggest that the severity of the exposure depends more on the magnitude of the exposed skin area than the concentration of cresylic acid. Therefore, the critical factor in dealing with an external physical exposure to cresylic acids is to minimize the extent and duration of the contact. To this end, the immediate response must be thorough flushing of the exposed areas with copious amounts of running water to remove all the cresylic acid in contact with the skin or eyes. Any contaminated clothing should be removed as quickly and carefully as possible during this process to avoid any additional skin contact.

Any exposed areas will have readily absorbed the cresylic acids and may be evidenced by a characteristic whitening of the skin. After thorough flushing with water, a solution consisting of 2 parts polyethylene glycol 400 to 1 part ethanol (PEG/EtOH) should be liberally applied to any affected skin (avoid contact with eyes), allowed to remain 15 to 30 seconds and then flushed away with fresh running water. Continue the cycling of PEG/EtOH and water for at least 15 minutes and then finish with thorough washing with soap and water. This decontamination procedure reduces the severity of the exposure, but does not completely eliminate damage to the skin or toxic effects. Medical attention should be sought as soon as possible.

Spill Containment & Clean-Up

Spill containment and cleanup of cresylic acids should only be performed by properly trained personnel employing an appropriate level of protective equipment as dictated by the extent of the spill. Small to medium spills on land should be surrounded by and absorbed onto inert clay absorbent and transferred to a disposal container. Larger land-spills should be diverted away from waterways, contained with booms, dikes or trenches, and collected in a vacuum truck. Any residual cresylic acids remaining after vacuuming should be cleaned up using the clay absorbent. All soils affected by the spill should be removed and placed in approved disposal containers.

Water spills are of particular concern due to the acute toxicity of cresylic acids to marine life. Clean up efforts should focus on containing the spill and quickly removing the cresylic acids that settle in deeper areas of the waterway. This can be aided greatly if the flow of water can be slowed or stopped. Further efforts should focus on removing as much of the dissolved cresylic acids as possible from the water using activated charcoal.

The composition and extent of any spill should be evaluated against local guidelines (ex. SARA Title III and RCRA in the U.S.) and reported to the proper agencies, if necessary. Any non disposable clean-up equipment should be thoroughly decontaminated with soap and water after use.

Source : SASOL / USA

Safe Handling of Cresols, Xylenols & Cresylic Acids

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Some significant points to note about Cresylic Acid

Below is a photo taken 10 years ago in the Irish Army Air Corps NDT shop,  part of the Avionics / ERF building complex. Ardrox 666 can be seen spilled on the ground where it was free to leach through a shore onto the grass verge outside. 

  • 25% of fresh Ardrox 666 used by the Air Corps was Cresylic Acid. This percentage was higher in waste Ardrox 666 as Dichloromethane evaporated.
  • That greenish / yellow stain dripping from the extractor fan is also Ardrox 666 from the air.

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